- Play as Hollow Ichigo
Successfully complete 23rd Story mode to unlock Hollow Ichigo.

- Play as Kuchiki Rukia
Successfully complete Story mode with Ichigo. Then, successfully complete Story mode with Yorouchi to unlock Kuchiki Rukia.

- Play as Aizen
Successfully complete Story mode with Ichigo. Then, successfully complete Story mode with Unmasked Komamura to unlock Aizen.

- 23rd Story mode
Successfully complete the first 22 Story modes to unlock 23rd Story mode.

- Play as Shigekuni Yamamoto Genryusai, Soi Fon, Ukitake, and Yorouchi
Successfully complete Story mode with Ichigo to unlock Shigekuni Yamamoto Genryusai, Soi Fon, Ukitake, and Yorouchi.

- Level 4 Attack cards
Successfully complete Challenge mode with Ichigo to unlock Level 4 Attack cards.

- Play as Tatsuki
Successfully complete Story mode with Ichigo. Then, successfully complete Story mode with Orhime to unlock Tatsuki.

- Play as Kusajika Yachiru
Successfully complete Story mode with Ichigo. Then, successfully complete Story mode with Zaraki Kenpachi to unlock Kusajika Yachiru.

- Survival mode
Successfully complete Story mode with all characters to unlock Survival mode.

- Play as Bonnie the boar
Successfully complete Story mode with Ganju to unlock Bonnie the boar.

- Time Attack mode
Successfully complete Story mode with all characters to unlock Time Attack mode.

- Play as Kon
Successfully complete Story mode with Ichigo. Then, successfully complete Story mode with Rukia to unlock Kon.