Go into the Urahara shop. Enter the password menu. Use one of the following actions on the touchscreen to obtain the corresponding effect:
Successfully complete the indicated task to unlock the corresponding character:
| Rangiku Matsumoto | Overcome her and Iduru together in Story mode. |
| Aizen Sousuke | Successfully complete Story mode Part A. |
| Ogihci | Successfully complete Story mode Part C 100%. |
| Shibata | Successfully complete Story mode Parts A through D 100%. |
| Kyugohanin | Successfully complete Story mode Parts A through D 100%. |
| Bonnie | Overcome Bonnie in Story mode. |
| Goteitaishi | Successfully complete Story mode Parts A through D 100%. |
| Tosen | Successfully complete Story mode Part A 100%. |
| Rukia Kuchiki | Successfully complete the first part of Story mode. |
| Shuhei Hisagi | Overcome him in Story mode. |
| Tsukaima | Successfully complete Story mode Parts A through D 100%. |
| Tatsuki | Successfully complete Story mode Part C 100%. |
| Soifon | Overcome her in Story mode. |
| Shrieker | Successfully complete Story mode Parts A through D 100%. |
| Ururu | Successfully complete Story mode Part A. |
| Hollows | Successfully complete Story mode 100%. |
| Don Kanonji | Successfully complete Story mode Part D. |
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| Ichimaru Gin | Successfully complete Story mode Part B 100%. |
| Menos-Grande | Successfully complete Story mode Parts A through D 100%. |
| Iduru Kira | Overcome him and Rangiku together in Story mode. |
| Kukaku | Successfully complete Story mode Part B. |
| Grandfisher | Successfully complete Story mode Parts A through D 100%. |
| Ririn | Successfully complete Story mode Part D 100%. |
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| Yachiru Kusajishi | Overcome her in Story mode. |
