- Major titles
Successfully complete the indicated Story mode to unlock the corresponding title:

Elec Major	Thunder Hero's Story mode
Earth Major	Earth Hero's Story mode
Fire Major	Fire Hero's Story mode
Water Major	Water Hero's Story mode

- Shadow of Darkness bonus quest
Successfully complete Story mode with all default characters and the 'Fire Major', 'Aqua Major', 'Rock Major', and 'Elec Major' titles to unlock the 'Shadow Of Darkness' bonus quest at Synethesia.

- Play as Zeke
Successfully complete all quests, including the 'Shadow Of Darkness' bonus quest, to unlock Zeke in Wi-Fi battles.

- Play as Asuka
Successfully complete Daichi's Story mode to unlock Asuka.

- Play as Gyamon
Successfully complete Guy's Story mode to unlock Gyamon.

- Play as Koki
Successfully complete Hibito's Story mode to unlock Koki.

- Play as Shura
Successfully complete Kairu's Story mode to unlock Shura.