- Play as Higashikata
Successfully complete Kantou Doubles with Sengoku and Akutsu to unlock Higashikata.

- Play as Osh*tari
Successfully complete Kantou Singles with Shishido to unlock Osh*tari.

- Play as Kisarazu Atsushi
Successfully complete Area Doubles with the Fuji Brothers to unlock Kisarazu Atsushi.

- Play as Inui
Successfully complete Iron Plate 1 to unlock Inui.

- Play as Kikumaru
Successfully complete Area Match Doubles with Fuji and Kawamura to unlock Kikumaru.

- Play as Kabaji
Successfully complete R-1 to unlock Kabaji.

- Play as Tezuka
Successfully complete the Nationals Singles No Miss Finish with Ryoma to unlock Tezuka. Notice: No points can be lost.

- Play as Sakurai
Successfully complete Area Doubles with Momoshiro and Kamio to unlock Sakurai.

- Play as Ibu
Successfully complete Area Singles with Kamio to unlock Ibu.

- Play as Sengoku
Successfully complete the Junior Selection to unlock Sengoku.

- Play as Oishi
Successfully complete Kantou MIX with Seigaku Team B to unlock Oishi.

- Play as Dan
Successfully complete Top Of Lefty with Ryoma to unlock Dan.

- Play as Atobe
Successfully complete Iron Plate 3 to unlock Atobe.

- Play as Minami
Successfully complete I-1 to unlock Minami.

- Play as Mizuki
Successfully complete Open Cup Singles with Ryoma to unlock Mizuki.

- Play as Kaneda
Successfully complete Area MIX to unlock Kaneda.

- Play as Akutsu
Successfully complete Area Singles with Muromachi to unlock Akutsu.

- Play as Akazawa
Successfully complete Area Singles with Mizuki to unlock Akazawa.

- Play as Tachibana
Successfully complete Kantou Singles with Ibu to unlock Tachibana.

- Play as Shinya
Successfully complete Iron Plate 2 (Doubles) to unlock Shinya.

- Play as Kaidou
Successfully complete the Seigaku Rankings Match to unlock Kaidou.