- Karakura Heroes match
Successfully complete all twenty Story missions under the Mission Battle option to unlock the Karakura Heroes match.

- Extra partners
Play Soul Road on the Normal or Hard difficulty setting with the indicated character. When a question is answered correctly, the answer will be the name of the character that is unlocked. You must hit the blue spot with at least 60% Trust so that the question appears.

Unohana	Play as Ishida or Final State Quincy Ishida
Keigo	Play as Ichigo or Bankai Ichigo
Tousen	Play as Gin
Kon	Play as Rukia or Shinigami Rukia
Karin	Play as Chad
Kojima Mizuiro	Play as Ichigo or Bankai Ichigo
Ururu	Play as Urahana
Hanatarou	Play as Ichigo or Bankai Ichigo
Isshin	Play as Chad
Ikkaku	Play as Renji or Bankai Renji
Kuukaku	Play as Yoruichi
Isane	Play as Hinamori
Iba Tetsuzaemon	Play as Rangiku
Yumichika	Play as Kenpachi
Yuzu	Play as Urahana

- Bonus characters
Successfully complete the indicated task to unlock the corresponding playable character:

Kyouraku Shunsui	Successfully complete Time Attack mode with Ukitake Jyuushirou.
Kurotsuchi Nemu	Successfully complete Time Attack mode with Kurotsuchi Mayuri.
Kusajishi Yachiru	Successfully complete Time Attack mode with Zaraki Kenpachi.
Ise Nanao	Successfully complete Time Attack mode with Kyouraku Shunsui.
Ishida Quincy Final Stage	Successfully complete Story Mission 6.
Renji Bankai	Successfully complete Story Mission 12.
Hitsugaya Bankai	Successfully complete Story Mission 9.
Komamura Sajin	Successfully complete Time Attack mode with Yamamoto Genryuusai Shigekuni.
Hisagi Shuuhei	Successfully complete Time Attack mode with Komamura Sajin.
Byakuya Bankai	Successfully complete Story Mission 17.
Rukia Shinigami	Successfully complete Time Attack mode with Kuchiki Rukia.
Ulquiorra	Successfully complete the Karakura Heroes match.

- EX Survival mode
Be victorious in at least ten battles in Survival mode to unlock EX Survival mode.