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Bonus characters
Overcome one of the following characters in the indicated chapter in Story mode to unlock them:
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| Grimmjaw | Overcome in Chapter 10 |
| Aaroniero | Overcome in Chapter 27 |
| Ichimaru Gin | Overcome in Chapter 47 |
| Ulquiorra | Overcome in Chapter 29 |
| Yami | Overcome in Chapter 6 |
| Noitora | Overcome in Chapter 26 |
| Aizen | Overcome in Chapter 49 |
| Szayel | Overcome in Chapter 32 |
| Shinji | Overcome in Chapter 3 |
| Nel (Adult) | Overcome in Chapter 41 |
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| Zomari | Overcome in Chapter 36 |
To unlock Filler Captain Amagai, earn money in Story mode, Survival mode, and Two Player Versus mode. He can then be purchased at Urahara's shop at random.
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Moves
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| Counter | Push Z. |
| Strong attack | Push B. |
| Special strong attack | Push Z + B. |
| Special Weak attack | Push Z + A. |
| Dash or Shunpo | Push C. |
| Slash combos | Shake Wii-mote. |
| Weak attack | Push A. |
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| Bankai | Push Z + shake Nunchuck. |
Additionally, the following moves can be done in Team Battle mode on the Wii-mote.
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| Summon your partner to attack briefly | Down. |
| Switch with your partner | Push Up. |
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| Summon CPU-controlled partner to fight with you | Z + Down. |
Some characters can also do a special move by pressing Z + shake Nunchuck twice:
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| Byakuya | White Imperial Sword |
| Ichigo | Hollow Mask |
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| Grimmjow | Death Gallon |
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